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The UEFA Champions League 2025/26 has begun, and for the first time, the final will be played at Hungary’s Puskás Aréna.
The new Champions League format continues for a second season, having started in 2024 and running through to 2027. The traditional group stage is gone, replaced by a single 36-team league table where every club plays eight matches against different opponents.
Our Champions League Predictions
21/10
Barcelona vs Olympiacos Piraeus
Home Win
Barcelona’s recent form has been inconsistent, highlighted by a 2-1 loss to PSG where they struggled defensively and lacked cohesion in the second half. Playing at the Camp Nou provides a significant advantage, with the team historically performing better on home soil. Considering Barcelona’s potential to bounce back and their home advantage, they are favored to secure a victory in this matchup.
Where to bet: Melbet, 22bet, Betjara
Arsenal vs Atlético Madrid
Draw or Atlético Madrid
Arsenal recently ended against Olympiacos with a 2-0 victory. However, Atlético Madrid presents a different challenge with their tactical discipline and strong defensive setup. In their previous encounters, Atlético has had the upper hand, including a 1-0 victory in the Europa League semi-finals.
Bayer Leverkusen vs PSG
Away win
Paris Saint-Germain (PSG) recently secured a dramatic 2-1 victory over Barcelona, with Gonçalo Ramos scoring a last-minute winner. In contrast, Bayer Leverkusen have shown vulnerabilities, drawing both of their opening matches against Copenhagen and PSV Eindhoven.
FC Copenhagen vs Dortmund
Away win
Borussia Dortmund have a strong record against FC Copenhagen, winning 3 out of their last 4 encounters, with the remaining match ending in a draw. FC Copenhagen, on the other hand, have struggled, scoring no goals in their recent Champions League matches.
Bayern Munich vs Club Brugge KV
Home Win
Bayern Munich recently dominated FC Pafos with a 5-1 victory. Club Brugge have won two away games in the Champions League. Bayern’s depth and quality, especially at home, make them favorites to win this matchup.
Eintracht Frankfurt vs Liverpool
Away win
Liverpool’s recent form in the Champions League has been commendable, with a strong track record in European competitions throughout the years. It could be challenging for Eintracht Frankfurt against a high-caliber team like Liverpool.
Where to bet: Melbet, 22bet, Betjara
Real Madrid vs Juventus
Home win
Real Madrid’s dominance at the Santiago BernabĂ©u is well-known, and their recent performances in the Champions League have been impressive. Juventus, on the other hand, has faced challenges in European competitions, as highlighted by their recent 2-2 draw against Villarreal. Real Madrid’s home advantage and current form make them strong contenders for a victory in this matchup.

Kairat Almaty vs PafosÂ
Over 2.5 Goals
It’s anticipated that the match will see multiple goals. Historical data also supports the likelihood of over 2.5 goals in such encounters.
22/10
Galatasaray vs Bodo/Glimt
Both teams to score
This will be the first-ever encounter between Galatasaray and Bodø/Glimt, making it a fascinating matchup. Galatasaray has been in impressive form, averaging 2.5 goals per match in the current season. Bodø/Glimt, seem strong after a notable 2-2 draw against Tottenham.
Atalanta vs Slavia Prague
Over 2.5 Goals
Atalanta has been known for their attacking style, often leading to high-scoring games. Their home advantage at the New Balance Arena could further bolster their offensive efforts. Given Atalanta’s attacking tendencies and Slavia Prague’s potential to capitalize on opportunities, an over 2.5 goals outcome appears probable.
Chelsea vs Ajax
Over 2.5 Goals & Both Teams to score
Historically, matches between Chelsea and Ajax have been high-scoring affairs. The most recent encounter in 2019 ended in a thrilling 4-4 draw. Chelsea’s recent form has been inconsistent, but their offensive capabilities remain strong. Ajax, has the potential to score, as evidenced by their previous matches. A combination of over 2.5 goals and BTTS is a compelling prediction.
Where to bet: Melbet, 22bet, Betjara
Previous Champions League predictions
Galatasaray vs Liverpool – OV2.5 Goals & Both Teams to Score (GG) ❌
Atalanta vs Club Brugge – Home & Over 2.5 Goals âś…
Chelsea vs Benfica – Chelsea Win âś…
Marseille vs Ajax – Over 2.5 Goalsâś…
Pafos vs Bayern – Bayern Win & OV 2.5 Goalsâś…
Napoli vs Sporting – Napoli Winâś…
Union Saint_Gilloise vs Newcastle – Home❌
Juventus vs Villarreal –Â GGâś…
Monaco vs Manchester City – Manchester City Win❌
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The article was last updated on Friday, 3rd October 2025

Results-driven and efficient professional with over 7 years of experience in football, iGaming, sports
content writing and social media management. All round lover of the game that sees football as so much more. Could be found writing about football or giving some off the charts punditry. Keen interest on the Premier League and Brazilian Football. Forgot to mention that I believe the Gunners will win the Champions League at some point in my lifetime.